Author/Editor | Kosec-Mikić, Tadeja; Milošev, Ingrid; Pihlar, Boris | |
Title | Vedenje zlitin Cu-xZn v boratnem pufru z dodatkom kloridnih ionov | |
Translated title | The bahaviour of Cu-xZn alloys in a borate solution containing chloride ions | |
Type | članek | |
Source | Mater Tehnol | |
Vol. and No. | Letnik 38, št. 6 | |
Publication year | 2004 | |
Volume | str. 349-52 | |
Language | slo | |
Abstract | The electrochemical behaviours of Cu-xZn alloys and Cu and Zn metals were studied in a slightly alkaline borate buffer solution, pH = 9.2, with and without the addition of aggressive chloride ions accross a wide concentration range. Various electrochemical techniques were used in the study and the results were discussed, considering both the metal/oxide and the oxide/electrolyte interfaces. In alkaline chloride solutions Cu-xZn alloys and Cu and Zn metals suffer from pitting corrosion. It was found that the general properties of Cu-xZn alloys resemble those of copper more than those of zinc. With increasing zinc content in the alloy ehe characteristics of zinc become more pronounced. | |
Summary | Preučevali smo vedenje zlitin Cu-xZn in posameznih kovinskih komponent v rahlo alkalni raztopini boratnega pufra, pH = 9,2, z dodatkom agresivnih kloridnih ionov in brez njih v širokem koncentracijskem območju. Pri delu smo uporabljali različne elektrokemijske metode in rezultate diskutirali upoštevaje fazno mejo kovina/oksid in oksid/elektrolit. V prisotnosti kloridnih ionov so zlitine in kovini podvržene jamičasti koroziji. Lastnosti zlitin Cu-xZn so bolj podobne bakru kot cinku. Ugotovili smo, da s povečanjem vsebnosti cinka postajajo bolj izrazite elektrokemijske lastnosti kovine cinka. | |
Descriptors | COPPER ZINC ALLOYS BUFFERS BORATES CHLORIDES CORROSION ELECTROCHEMISTRY MATERIALS TESTING |