Author/Editor | Seppen, A; Muševič, I; Maret, G; Žekš, B; Wyder, P; Blinc, R | |
Title | Temperature dependence of the rotatory power in the SmC* phase of DOBAMBC | |
Type | članek | |
Source | J Phys France | |
Vol. and No. | Letnik 49 | |
Publication year | 1988 | |
Volume | str. 1569-73 | |
Language | eng | |
Abstract | High resolution measurements of the temperature dependence of the optical rotatory power P(T) in the SmC* phase of the ferroelectric liquid crystal DOBAMBC are presented. Special emphasis is on the region near the SmC*-SmA transition. These data together with measurements of the pitch allow for a determination of the molecular tilt angle in the helicoidal structure. This is believed to be the first optical measurement of the tilt in an unperturbed SmC* phase, i.e. without unwinding of the helix. The measurements of the tilt angle in this case are compared with those on the unwound structure and are briefly discussed in connection with theory. | |
Descriptors | CRYSTALLOGRAPHY THERMODYNAMICS |