Author/Editor		Kutnjak-Urbanc, B; Žekš, B
Title		Microscopic origin of spontaneous polarization in ferroelectric Sc* liquid crystals
Type		članek
Source		Liquid crystals
Vol. and No.		Letnik 18, št. 3
Publication year		1995
Volume		str. 483-8
Language		eng
Abstract		The origin of spontaneous polarization in the ferroelectric smectic C phase in investigated within a mean-field microscopic model which describes the coupling between the tilt of moelcules from the normal to the smectic layers and the rotation of a molecule around its long axis. The mean-field potential is studied which takes into account a chiral polar and a non-chiral quadrupolar biasing of the rotation of molecules around the molecular long axes. Each molecule is characterized by three transverse molecular axes: the chiral axis which turns parallel to the macroscopic C2 axis at small tilts, the polar axis in the direction of the transverse dipole moment and the quadrupolar axis which tends to be parallel to the C2 axis at very large tilts. A numerical analysis of the model shows that there are four different types of spontaneous polarization dependent on the temperature, including the sign-reversal type. The influence of three microscopic parameters, i.e. two angles between the three characteristic axes and the relative strength of the chiral versus the non-chiral biasing, on the type of spontaneous polarization is investigated. The relationship between the microscopic and the equivalent Landau model is established and discussed.
Descriptors		CRYSTALLOGRAPHY MODELS, THEORETICAL