Author/Editor | Milačič, R; Dolinšek, F | |
Title | Determination of cadmium and lead in aerosols in the Zasavje region in Slovenia employing slurry electrothermal atomic absortption spectrometry | |
Type | članek | |
Source | Int J Environ Anal Chem | |
Vol. and No. | Letnik 57 | |
Publication year | 1994 | |
Volume | str. 329-37 | |
Language | eng | |
Abstract | Investigations of air pollution were carried out in the Zasavje urban industrialized region in Slovenia. Cadmium and lead were measured in respirable (less th. 2.5 micrometer) and inhalable (2.5-10 micrometer) aerosols. Special pumps were equpped with Nucleopore-Costar polycarbonate membrane filters. Cadmium and lead were measured in those filters by slurry electrothermal atomic absorption spectrometry (ETAAS) on a laboratory assembled atomic absorption spectrometer with a graphite cup atomizer. A reliability of the employed technique was proved by analysis of the same filters with classical dissolution of aerosol particles in diluted nitric acid and measurement of cadmium and lead by flame atomic absorption spectrometry (FAAS). Good agreement (+- 5-10 percent) of the results was obtained between the two techniques for both elements. The study indicated that cadmium and lead in a contaminated area prevailed in the respirable (less th. 2.5 micrometer) aerosols. The employed technique was sensitive enough for measurment of cadmium and lead also in non-polluted areas. | |
Descriptors | AIR POLLUTANTS CADMIUM LEAD SLOVENIA AEROSOLS SPECTROPHOTOMETRY, ATOMIC ABSORPTION |