Author/Editor | Prodan, A; Vene, N; Sevšek, F; Hudomalj, M | |
Title | The crystal structure of epitaxially grown SnO2 thin films | |
Type | članek | |
Source | Thin Solid Films | |
Vol. and No. | Letnik 147 | |
Publication year | 1987 | |
Volume | str. 313-9 | |
Language | eng | |
Abstract | It is shown by computer simulation of the transmission electron diffraction patterns and by structural considerations that the recently reported thin film for beta-Sn=2 is equivalent to the high pressure form SnO2-II. It crystallizes in a columbite-like structure either under the influence of the substrate in the case of epitaxial oxidation of alfa-SnO to SnO2 or under the influence of volume contraction conditioned by enhanced pressure and/or temperature during the cassiteritecolumbite transformation. The columbite-brookite-cassiterite structural relationship given and the possibility of the existence of a thin film fluorite-like polymorph is discussed. | |
Descriptors | CRYSTALLOGRAPHY TIN COMPOUNDS |