Author/Editor     Prodan, A; Vene, N; Sevšek, F; Hudomalj, M
Title     The crystal structure of epitaxially grown SnO2 thin films
Type     članek
Source     Thin Solid Films
Vol. and No.     Letnik 147
Publication year     1987
Volume     str. 313-9
Language     eng
Abstract     It is shown by computer simulation of the transmission electron diffraction patterns and by structural considerations that the recently reported thin film for beta-Sn=2 is equivalent to the high pressure form SnO2-II. It crystallizes in a columbite-like structure either under the influence of the substrate in the case of epitaxial oxidation of alfa-SnO to SnO2 or under the influence of volume contraction conditioned by enhanced pressure and/or temperature during the cassiteritecolumbite transformation. The columbite-brookite-cassiterite structural relationship given and the possibility of the existence of a thin film fluorite-like polymorph is discussed.
Descriptors     CRYSTALLOGRAPHY
TIN COMPOUNDS